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Reactions’ Mechanisms and Applications of Hydrogen Peroxide

Received: 15 May 2020     Accepted: 1 June 2020     Published: 17 June 2020
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Abstract

Hydrogen peroxide is a key substance in the appearance of life and maintenance of the life-supporting conditions on the Earth. Electron transfer processes between H2O2 and various reducers are of major interest for the environment, natural life, technology, etc. An overview of structure, proprieties and main reactions of hydrogen peroxide in model and real systems is presented. The authors try to find the answers to the following questions: why this substance has the unique and specific dual reduction-oxidation properties, what is the connection between its structure and reactions, what role it plays in the catalytic reduction processes occurring in the natural environment and technological systems, accompanied by the formation of intermediate compounds, active radicals, complete and partial charge transfer complexes, etc. The thermodynamic possibility of the synchronous two-electron transfer during the inner sphere reaction with the involvement of metal ion complexes capable of changing the valence by two units is discussed. The role of the partial charge transfer structures which combine the properties of the initial reagents and the expected reaction products is demonstrated. Such complexes can be decomposed both reversibly and irreversibly. In case when the single-electron transfer is thermodynamically preferable, the main oxidizing particle is OH-radical, capable to interact non-selectively with almost all the water-soluble organic substances. Special attention is paid to the photo initiation of peroxidase transformation processes. The results of our multi-annual research of these issues are reported.

Published in American Journal of Physical Chemistry (Volume 9, Issue 2)
DOI 10.11648/j.ajpc.20200902.13
Page(s) 36-44
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Hydrogen Peroxide, Reduction-oxidation, Catalytic Processes, Electron Transfer, Metal Complexes, Water Quality

References
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    Gheorghe Duca, Sergey Travin. (2020). Reactions’ Mechanisms and Applications of Hydrogen Peroxide. American Journal of Physical Chemistry, 9(2), 36-44. https://doi.org/10.11648/j.ajpc.20200902.13

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    ACS Style

    Gheorghe Duca; Sergey Travin. Reactions’ Mechanisms and Applications of Hydrogen Peroxide. Am. J. Phys. Chem. 2020, 9(2), 36-44. doi: 10.11648/j.ajpc.20200902.13

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    AMA Style

    Gheorghe Duca, Sergey Travin. Reactions’ Mechanisms and Applications of Hydrogen Peroxide. Am J Phys Chem. 2020;9(2):36-44. doi: 10.11648/j.ajpc.20200902.13

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  • @article{10.11648/j.ajpc.20200902.13,
      author = {Gheorghe Duca and Sergey Travin},
      title = {Reactions’ Mechanisms and Applications of Hydrogen Peroxide},
      journal = {American Journal of Physical Chemistry},
      volume = {9},
      number = {2},
      pages = {36-44},
      doi = {10.11648/j.ajpc.20200902.13},
      url = {https://doi.org/10.11648/j.ajpc.20200902.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20200902.13},
      abstract = {Hydrogen peroxide is a key substance in the appearance of life and maintenance of the life-supporting conditions on the Earth. Electron transfer processes between H2O2 and various reducers are of major interest for the environment, natural life, technology, etc. An overview of structure, proprieties and main reactions of hydrogen peroxide in model and real systems is presented. The authors try to find the answers to the following questions: why this substance has the unique and specific dual reduction-oxidation properties, what is the connection between its structure and reactions, what role it plays in the catalytic reduction processes occurring in the natural environment and technological systems, accompanied by the formation of intermediate compounds, active radicals, complete and partial charge transfer complexes, etc. The thermodynamic possibility of the synchronous two-electron transfer during the inner sphere reaction with the involvement of metal ion complexes capable of changing the valence by two units is discussed. The role of the partial charge transfer structures which combine the properties of the initial reagents and the expected reaction products is demonstrated. Such complexes can be decomposed both reversibly and irreversibly. In case when the single-electron transfer is thermodynamically preferable, the main oxidizing particle is OH-radical, capable to interact non-selectively with almost all the water-soluble organic substances. Special attention is paid to the photo initiation of peroxidase transformation processes. The results of our multi-annual research of these issues are reported.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Reactions’ Mechanisms and Applications of Hydrogen Peroxide
    AU  - Gheorghe Duca
    AU  - Sergey Travin
    Y1  - 2020/06/17
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajpc.20200902.13
    DO  - 10.11648/j.ajpc.20200902.13
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 36
    EP  - 44
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20200902.13
    AB  - Hydrogen peroxide is a key substance in the appearance of life and maintenance of the life-supporting conditions on the Earth. Electron transfer processes between H2O2 and various reducers are of major interest for the environment, natural life, technology, etc. An overview of structure, proprieties and main reactions of hydrogen peroxide in model and real systems is presented. The authors try to find the answers to the following questions: why this substance has the unique and specific dual reduction-oxidation properties, what is the connection between its structure and reactions, what role it plays in the catalytic reduction processes occurring in the natural environment and technological systems, accompanied by the formation of intermediate compounds, active radicals, complete and partial charge transfer complexes, etc. The thermodynamic possibility of the synchronous two-electron transfer during the inner sphere reaction with the involvement of metal ion complexes capable of changing the valence by two units is discussed. The role of the partial charge transfer structures which combine the properties of the initial reagents and the expected reaction products is demonstrated. Such complexes can be decomposed both reversibly and irreversibly. In case when the single-electron transfer is thermodynamically preferable, the main oxidizing particle is OH-radical, capable to interact non-selectively with almost all the water-soluble organic substances. Special attention is paid to the photo initiation of peroxidase transformation processes. The results of our multi-annual research of these issues are reported.
    VL  - 9
    IS  - 2
    ER  - 

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Author Information
  • Institute of Chemistry, Chisinau, Republic of Moldova

  • Semenov Federal Research Centre for Chemical Physics of the Russian Academy of Sciences, Moscow, Russian Federation

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