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Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent

Received: 7 September 2020     Accepted: 24 September 2020     Published: 14 October 2020
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Abstract

Surfactants are amphiphilic compounds that are widely used in various technological fields and biological systems. In many of these applications, mixtures of amphiphiles in organic solvents are employed for better performance The work aims at establishing the extent of ideality or otherwise in the mixed micelles of n-alkyl trimethylammonium bromide, (n = 14 and 16 for TTABr and CTABr respectively), in water (AQ) and water-monoethanolamine (AQ-MEA) at different mole fractions (0.1 to 0.6) and temperatures by Conductance measurement.: The values of the critical micelle concentration (Cmx) obtained in AQ, and AQ-MEA were lower than that obtained assuming an ideal mixing system. Substantial deviation from ideality was observed in the presence of AQ-MEA at all temperatures, suggestive of more favourable association of the surfactants in MEA solvent. The composition (χ1) of the mixed micelles obtained in the context of Rubingh’s model showed that the micelles of CTABr were dominant, and the values of the interaction parameters (βmx) were negative in AQ and AQ-MEA media with more synergistic interaction in the latter case at 0.1:0.9 mole fraction ratio at a particular temperature. The values of the activity coefficients (fTTABr, fCTABr) were below unity, and the evaluation of the energetics of micellization showed that the process was spontaneous and feasible.

Published in American Journal of Physical Chemistry (Volume 9, Issue 4)
DOI 10.11648/j.ajpc.20200904.11
Page(s) 86-92
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Surfactant, Mixed-Micelles, Conductance Measurements

References
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Cite This Article
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    Osundiya Medinat Olubunmi, Olowu Rasaq Adewale, Olaseni Segun Esan, Aboluwoye Christopher Olumuyiwa. (2020). Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent. American Journal of Physical Chemistry, 9(4), 86-92. https://doi.org/10.11648/j.ajpc.20200904.11

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    ACS Style

    Osundiya Medinat Olubunmi; Olowu Rasaq Adewale; Olaseni Segun Esan; Aboluwoye Christopher Olumuyiwa. Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent. Am. J. Phys. Chem. 2020, 9(4), 86-92. doi: 10.11648/j.ajpc.20200904.11

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    AMA Style

    Osundiya Medinat Olubunmi, Olowu Rasaq Adewale, Olaseni Segun Esan, Aboluwoye Christopher Olumuyiwa. Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent. Am J Phys Chem. 2020;9(4):86-92. doi: 10.11648/j.ajpc.20200904.11

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  • @article{10.11648/j.ajpc.20200904.11,
      author = {Osundiya Medinat Olubunmi and Olowu Rasaq Adewale and Olaseni Segun Esan and Aboluwoye Christopher Olumuyiwa},
      title = {Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent},
      journal = {American Journal of Physical Chemistry},
      volume = {9},
      number = {4},
      pages = {86-92},
      doi = {10.11648/j.ajpc.20200904.11},
      url = {https://doi.org/10.11648/j.ajpc.20200904.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20200904.11},
      abstract = {Surfactants are amphiphilic compounds that are widely used in various technological fields and biological systems. In many of these applications, mixtures of amphiphiles in organic solvents are employed for better performance The work aims at establishing the extent of ideality or otherwise in the mixed micelles of n-alkyl trimethylammonium bromide, (n = 14 and 16 for TTABr and CTABr respectively), in water (AQ) and water-monoethanolamine (AQ-MEA) at different mole fractions (0.1 to 0.6) and temperatures by Conductance measurement.: The values of the critical micelle concentration (Cmx) obtained in AQ, and AQ-MEA were lower than that obtained assuming an ideal mixing system. Substantial deviation from ideality was observed in the presence of AQ-MEA at all temperatures, suggestive of more favourable association of the surfactants in MEA solvent. The composition (χ1) of the mixed micelles obtained in the context of Rubingh’s model showed that the micelles of CTABr were dominant, and the values of the interaction parameters (βmx) were negative in AQ and AQ-MEA media with more synergistic interaction in the latter case at 0.1:0.9 mole fraction ratio at a particular temperature. The values of the activity coefficients (fTTABr, fCTABr) were below unity, and the evaluation of the energetics of micellization showed that the process was spontaneous and feasible.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Micellization and Interaction of Cationic Surfactants with Different Hydrophobic Group in Polar Organic Solvent
    AU  - Osundiya Medinat Olubunmi
    AU  - Olowu Rasaq Adewale
    AU  - Olaseni Segun Esan
    AU  - Aboluwoye Christopher Olumuyiwa
    Y1  - 2020/10/14
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    N1  - https://doi.org/10.11648/j.ajpc.20200904.11
    DO  - 10.11648/j.ajpc.20200904.11
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 86
    EP  - 92
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20200904.11
    AB  - Surfactants are amphiphilic compounds that are widely used in various technological fields and biological systems. In many of these applications, mixtures of amphiphiles in organic solvents are employed for better performance The work aims at establishing the extent of ideality or otherwise in the mixed micelles of n-alkyl trimethylammonium bromide, (n = 14 and 16 for TTABr and CTABr respectively), in water (AQ) and water-monoethanolamine (AQ-MEA) at different mole fractions (0.1 to 0.6) and temperatures by Conductance measurement.: The values of the critical micelle concentration (Cmx) obtained in AQ, and AQ-MEA were lower than that obtained assuming an ideal mixing system. Substantial deviation from ideality was observed in the presence of AQ-MEA at all temperatures, suggestive of more favourable association of the surfactants in MEA solvent. The composition (χ1) of the mixed micelles obtained in the context of Rubingh’s model showed that the micelles of CTABr were dominant, and the values of the interaction parameters (βmx) were negative in AQ and AQ-MEA media with more synergistic interaction in the latter case at 0.1:0.9 mole fraction ratio at a particular temperature. The values of the activity coefficients (fTTABr, fCTABr) were below unity, and the evaluation of the energetics of micellization showed that the process was spontaneous and feasible.
    VL  - 9
    IS  - 4
    ER  - 

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Author Information
  • Department of Chemistry, Lagos State University, Lagos, Nigeria

  • Department of Chemistry, Lagos State University, Lagos, Nigeria

  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

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