| Peer-Reviewed

Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar

Received: 9 October 2021     Accepted: 1 November 2021     Published: 10 November 2021
Views:       Downloads:
Abstract

The intensification of agricultural, domestic and industrial activities leads to the increasing contamination of groundwater and surface water by nitrates. Indeed, agricultural runoff, septic tank effluents, landfill leachates or wastewater treatment plant effluents contribute to this nitrification, yet drinking water containing high nitrate content can cause health problems. The study examines the improvement of nitrate removal in synthetic water solution by adsorption on banana peel’s activated carbon (BPAC). Different effects of physicochemical parameters, such as the optimal contact time of BPAC in solution, the pH of the nitrate solution, the initial concentration of nitrate solution, the BPAC mass, and the temperature were evaluated. The study revealed that BPAC has a low nitrate adsorption capacity under normal laboratory conditions. However, this adsorption capacity of BPAC increases with increasing of temperature and initial content of nitrate, while it decreases with increasing BPAC mass. For a content of 100 mg/L nitrate solution, the maximum adsorption capacity was 0, 687 mg/g for an equilibrium time of 180 min. Nitrate adsorption is optimal in acidic media (pH=3). The application of kinetic models to the experimental data showed that the mechanism of nitrate adsorption on BPAC obeys pseudo-first order kinetics. The Freundlich isotherm perfectly describes the mechanism of nitrate adsorption on BPAC.

Published in American Journal of Physical Chemistry (Volume 10, Issue 4)
DOI 10.11648/j.ajpc.20211004.13
Page(s) 59-66
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Adsorption, Nitrates, Activated Carbon, Banana Peels, Models

References
[1] Baggio, G., Qadir, M., & Smakhtin, V. (2021). Freshwater availability status across countries for human and ecosystem needs. Science of The Total Environment, 792, 148230.
[2] Murgulet, D., & Tick, G. R. (2013). Understanding the sources and fate of nitrate in a highly developed aquifer system. Journal of Contaminant Hydrology, 155, 69–81.
[3] Lockhart, K. M., King, A. M., & Harter, T. (2013). Identifying sources of groundwater nitrate contamination in a large alluvial groundwater basin with highly diversified intensive agricultural production. Journal of Contaminant Hydrology, 151, 140–154.
[4] Yoshino, H., Tokumura, M., & Kawase, Y. (2014). Simultaneous removal of nitrate, hydrogen peroxide and phosphate in semiconductor acidic wastewater by zero-valent iron. Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering, 49 (9), 998–1006.
[5] Chen, S., Wu, W., Hu, K., & Li, W. (2010). The effects of land use change and irrigation water resource on nitrate contamination in shallow groundwater at county scale. Ecological Complexity, 7 (2), 131–138.
[6] Wu, Y., Wang, Y., Wang, J., Xu, S., Yu, L., Philippe, C., & Wintgens, T. (2016). Nitrate removal from water by new polymeric adsorbent modified with amino and quaternary ammonium groups: Batch and column adsorption study. Journal of the Taiwan Institute of Chemical Engineers, 66, 191–199.
[7] Mazarji, M., Aminzadeh, B., Baghdadi, M., & Bhatnagar, A. (2017a). Removal of nitrate from aqueous solution using modified granular activated carbon. Journal of Molecular Liquids, 233, 139–148.
[8] Manjunath, S. V., & Kumar, M. (2018). Evaluation of single-component and multi-component adsorption of metronidazole, phosphate and nitrate on activated carbon from Prosopıs julıflora. Chemical Engineering Journal, 346, 525–534.
[9] WHO, W. H. O. (2017). Guidelines for Drinking-water Quality fourth edition incorporating the first addendum. New York, USA.
[10] USEPA, U. E. P. A. (2018). 2018 Edition of the Drinking Water Standards and Health Advisories Tables (EPA 822-F-18-001).
[11] Ao, L., Xia, F., Ren, Y., Xu, J., Shi, D., Zhang, S., … He, Q. (2019). Enhanced nitrate removal by micro-electrolysis using Fe0 and surfactant modified activated carbon. Chemical Engineering Journal, 357, 180–187.
[12] Berkani, I., Belkacem, M., Trari, M., & Lapicque, F. (2019). Journal of Environmental Chemical Engineering Assessment of electrocoagulation based on nitrate removal, for treating and recycling the Saharan groundwater desalination reverse osmosis concentrate for a sustainable management of Albien resource. Journal of Environmental Chemical Engineering, 7 (2), 102951.
[13] Epsztein, R., Nir, O., Lahav, O., & Green, M. (2015). Selective nitrate removal from groundwater using a hybrid nanofiltration-reverse osmosis filtration scheme. Chemical Engineering Journal, 279, 372–378.
[14] Schoeman, J. J., & Steyn, A. (2003). Nitrate removal with reverse osmosis in a rural area in South Africa. Desalination, 155 (1), 15–26.
[15] Ma, X., Li, M., Feng, C., & He, Z. (2020). Electrochemical nitrate removal with simultaneous magnesium recovery from a mimicked RO brine assisted by in situ chloride ions. Journal of Hazardous Materials, 388, 122085.
[16] Dobi-brice, K. K., Lynda, E., Zoungranan, Y., & Tchirioua, E. (2020). Theoretical Characteristics of Deactivated Lichens Fixed Bed Column for the Crystal Violet and. American Journal of Water Resources, 8 (2), 69–77.
[17] Satayeva, A. R., Howell, C. A., Korobeinyk, A. V., Jandosov, J., Inglezakis, V. J., Mansurov, Z. A., & Mikhalovsky, S. V. (2018). Investigation of rice husk derived activated carbon for removal of nitrate contamination from water. Science of the Total Environment, 630, 1237–1245.
[18] Nunell, G. V., Fernandez, M. E., Bonelli, P. R., & Cukierman, A. L. (2015). Nitrate uptake improvement by modified activated carbons developed from two species of pine cones. Journal of Colloid and Interface Science, 440, 102–108.
[19] Jin, X., Jiang, M., Shan, X., Pei, Z., & Chen, Z. (2008). Adsorption of methylene blue and orange II onto unmodified and surfactant-modified zeolite. Journal of Colloid and Interface Science, 328 (2), 243–247.
[20] Lagergren, S., Svenska, B. K., & Handl, V. (1996). “Removal of Arsenite and Arsenate Ions from Aqueous Solution by Basic Yttrium Carbonate” (as cited by Wasey et al.). Water Research, 30 (5), 1143 – 1148.
[21] Divband Hafshejani, L., Hooshmand, A., Naseri, A. A., Mohammadi, A. S., Abbasi, F., & Bhatnagar, A. (2016). Removal of nitrate from aqueous solution by modified sugarcane bagasse biochar. Ecological Engineering, 95, 101–111.
[22] Ho, Y.., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34 (5), 451–465.
[23] Reghioua, A., Barkat, D., Jawad, A. H., Abdulhameed, A. S., & Khan, M. R. (2021). Synthesis of Schiff’s base magnetic crosslinked chitosan-glyoxal/ZnO/Fe3O4 nanoparticles for enhanced adsorption of organic dye: Modeling and mechanism study. Sustainable Chemistry and Pharmacy, 20, 100379.
[24] Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40 (9), 1361–1403.
[25] Freundlich, H. M. F. (1906). Uber die adsorption in losungen. Zeitschrift Fur Physikalische Chemie-Leipzig, 57, 385–470.
[26] Kono, H., & Kusumoto, R. (2015). Removal of anionic dyes in aqueous solution by flocculation with cellulose ampholytes. Journal of Water Process Engineering, 7, 83–93.
[27] Ruthven, D. M. (1984). Principles of adsorption and adsorption processes. (Wiley). New York.
[28] Crini, G., & Badot, P.-M. (2008). Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies: A review of recent literature. Progress in Polymer Science, 33 (4), 399–447.
[29] Zhang, D. Y. C. (2014). Adsorption kinetics, isotherm and thermodynamics studies of flavones from Vaccinium bracteatum Thunb leaves on NKA-2 resin. Chem Eng J, 254, 579–585.
[30] Elmoubarki, R., Mahjoubi, F. Z., Tounsadi, H., Moustadraf, J., Abdennouri, M., Zouhri, A., … Barka, N. (2015). Adsorption of textile dyes on raw and decanted Moroccan clays: Kinetics, equilibrium and thermodynamics. Water Resources and Industry, 9, 16–29.
[31] Shukla, A., Zhang, Y.-H., Dubey, P., Margrave, J.., & Shukla, S. S. (2002). The role of sawdust in the removal of unwanted materials from water. Journal of Hazardous Materials, 95 (1–2), 137–152.
[32] Stavrinou, A., Aggelopoulos, C. A., & Tsakiroglou, C. D. (2018). Exploring the adsorption mechanisms of cationic and anionic dyes onto agricultural waste peels of banana, cucumber and potato: Adsorption kinetics and equilibrium isotherms as a tool. Journal of Environmental Chemical Engineering, 6 (6), 6958–6970.
[33] Cho, D. W., Chon, C. M., Kim, Y., Jeon, B. H., Schwartz, F. W., Lee, E. S., & Song, H. (2011). Adsorption of nitrate and Cr(VI) by cationic polymer-modified granular activated carbon. Chemical Engineering Journal, 175 (1), 298–305.
[34] Li, Y., Du, Q., Liu, T., Sun, J., Jiao, Y., Xia, Y., … Wu, D. (2012). Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto graphene. Materials Research Bulletin, 47 (8), 1898–1904.
[35] Dobi-brice, K. K., Lynda, E., Zoungranan, Y., Sévariste, K. K., & Tchirioua, E. (2020). Use of deactivated lichens for the adsorption of two toxic dyes: crystal violet and methyl red. Asian Journal of Science AndTechnology, 11 (4), 10911–10919.
[36] Nassar, H., Zyoud, A., El-Hamouz, A., Tanbour, R., Halayqa, N., & Hilal, H. S. (2020). Aqueous nitrate ion adsorption/desorption by olive solid waste-based carbon activated using ZnCl2. Sustainable Chemistry and Pharmacy, 18, 100335.
[37] Katal, R., Baei, M. S., Rahmati, H. T., & Esfandian, H. (2012). Kinetic, isotherm and thermodynamic study of nitrate adsorption from aqueous solution using modified rice husk. Journal of Industrial and Engineering Chemistry, 18 (1), 295–302.
[38] Mazarji, M., Aminzadeh, B., Baghdadi, M., & Bhatnagar, A. (2017b). Removal of nitrate from aqueous solution using modified granular activated carbon. Journal of Molecular Liquids, 233, 139–148.
[39] Abu, A., & Abdullah, N. (2020). Sorption and thermodynamic study of nitrate removal by using Amberlite IRA 900 (AI900) resin. Materials Today: Proceedings, 41, 102–108.
[40] Dobi-brice, K. K., Lynda, E., Tchirioua, E., & Zoungranan, Y. (2018). Biosorption of Methylene Blue and Orange II on deactivated lichen Parmotrema dilatatum : Modeling and kinetic studies. Australian Journal of Basic and Applied Sciences, 12 (12), 83–89.
[41] Shoukat, S., Bhatti, H. N., Iqbal, M., & Noreen, S. (2017). Mango stone biocomposite preparation and application for crystal violet adsorption: A mechanistic study. Microporous and Mesoporous Materials, 239, 180–189.
Cite This Article
  • APA Style

    Yacouba Zoungranan, Kouassi Kouadio Dobi-Brice, Koutouan Djako Oscar Eric, Sombo Anselme Stanislas, Ekou Tchirioua, et al. (2021). Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar. American Journal of Physical Chemistry, 10(4), 59-66. https://doi.org/10.11648/j.ajpc.20211004.13

    Copy | Download

    ACS Style

    Yacouba Zoungranan; Kouassi Kouadio Dobi-Brice; Koutouan Djako Oscar Eric; Sombo Anselme Stanislas; Ekou Tchirioua, et al. Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar. Am. J. Phys. Chem. 2021, 10(4), 59-66. doi: 10.11648/j.ajpc.20211004.13

    Copy | Download

    AMA Style

    Yacouba Zoungranan, Kouassi Kouadio Dobi-Brice, Koutouan Djako Oscar Eric, Sombo Anselme Stanislas, Ekou Tchirioua, et al. Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar. Am J Phys Chem. 2021;10(4):59-66. doi: 10.11648/j.ajpc.20211004.13

    Copy | Download

  • @article{10.11648/j.ajpc.20211004.13,
      author = {Yacouba Zoungranan and Kouassi Kouadio Dobi-Brice and Koutouan Djako Oscar Eric and Sombo Anselme Stanislas and Ekou Tchirioua and Ekou Lynda},
      title = {Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar},
      journal = {American Journal of Physical Chemistry},
      volume = {10},
      number = {4},
      pages = {59-66},
      doi = {10.11648/j.ajpc.20211004.13},
      url = {https://doi.org/10.11648/j.ajpc.20211004.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20211004.13},
      abstract = {The intensification of agricultural, domestic and industrial activities leads to the increasing contamination of groundwater and surface water by nitrates. Indeed, agricultural runoff, septic tank effluents, landfill leachates or wastewater treatment plant effluents contribute to this nitrification, yet drinking water containing high nitrate content can cause health problems. The study examines the improvement of nitrate removal in synthetic water solution by adsorption on banana peel’s activated carbon (BPAC). Different effects of physicochemical parameters, such as the optimal contact time of BPAC in solution, the pH of the nitrate solution, the initial concentration of nitrate solution, the BPAC mass, and the temperature were evaluated. The study revealed that BPAC has a low nitrate adsorption capacity under normal laboratory conditions. However, this adsorption capacity of BPAC increases with increasing of temperature and initial content of nitrate, while it decreases with increasing BPAC mass. For a content of 100 mg/L nitrate solution, the maximum adsorption capacity was 0, 687 mg/g for an equilibrium time of 180 min. Nitrate adsorption is optimal in acidic media (pH=3). The application of kinetic models to the experimental data showed that the mechanism of nitrate adsorption on BPAC obeys pseudo-first order kinetics. The Freundlich isotherm perfectly describes the mechanism of nitrate adsorption on BPAC.},
     year = {2021}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Reduction of Nitrate Content in Water by the Use of Banana Peels Biochar
    AU  - Yacouba Zoungranan
    AU  - Kouassi Kouadio Dobi-Brice
    AU  - Koutouan Djako Oscar Eric
    AU  - Sombo Anselme Stanislas
    AU  - Ekou Tchirioua
    AU  - Ekou Lynda
    Y1  - 2021/11/10
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajpc.20211004.13
    DO  - 10.11648/j.ajpc.20211004.13
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 59
    EP  - 66
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20211004.13
    AB  - The intensification of agricultural, domestic and industrial activities leads to the increasing contamination of groundwater and surface water by nitrates. Indeed, agricultural runoff, septic tank effluents, landfill leachates or wastewater treatment plant effluents contribute to this nitrification, yet drinking water containing high nitrate content can cause health problems. The study examines the improvement of nitrate removal in synthetic water solution by adsorption on banana peel’s activated carbon (BPAC). Different effects of physicochemical parameters, such as the optimal contact time of BPAC in solution, the pH of the nitrate solution, the initial concentration of nitrate solution, the BPAC mass, and the temperature were evaluated. The study revealed that BPAC has a low nitrate adsorption capacity under normal laboratory conditions. However, this adsorption capacity of BPAC increases with increasing of temperature and initial content of nitrate, while it decreases with increasing BPAC mass. For a content of 100 mg/L nitrate solution, the maximum adsorption capacity was 0, 687 mg/g for an equilibrium time of 180 min. Nitrate adsorption is optimal in acidic media (pH=3). The application of kinetic models to the experimental data showed that the mechanism of nitrate adsorption on BPAC obeys pseudo-first order kinetics. The Freundlich isotherm perfectly describes the mechanism of nitrate adsorption on BPAC.
    VL  - 10
    IS  - 4
    ER  - 

    Copy | Download

Author Information
  • Department of Mathematics, Physics and Chemistry, University Peleforo Gon Coulibaly, Korhogo, C?te d’Ivoire

  • Department of Chemistry, University Nangui Abrogoua, Abidjan, C?te d’Ivoire

  • Doctoral School of Science, Technology and Sustainable Agriculture, University Félix Houpho?t-Boigny, Abidjan, C?te d’Ivoire

  • Department of Chemistry, University Nangui Abrogoua, Abidjan, C?te d’Ivoire

  • Department of Chemistry, University Nangui Abrogoua, Abidjan, C?te d’Ivoire

  • Department of Chemistry, University Nangui Abrogoua, Abidjan, C?te d’Ivoire

  • Sections